温度对铂钽复合阳极电化学性能的影响
Effect of Temperature on Electrochemical Properties of Pt/Ta Composite Anode
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摘要: 对铂钽复合阳极在200 mA/cm2的电流密度下进行了恒电流试验,通过测量动电位极化曲线以及电化学阻抗谱,研究了阳极在不同温度海水中的电化学行为,利用扫描电镜(SEM)及能谱仪(EDS)对阳极形貌及成分进行了分析.电化学试验结果表明,铂钽复合阳极能承载较大的电流密度:随温度的降低,法拉第电荷传递电阻增大,阳极电化学催化活性有所下降.SEM分析结果表明,阳极表面有微裂纹,阳极工作时表面有大量气体析出,加速了阳极的溶解.Abstract: Pt/Ta composite anode was tested at a constant current density of 200 mA/cm2.The electrochemical properties was characterized by potentindynamic polarization curves and electrochemical impedance spectroscopy (EIS) in seawater at different temperatures,in combination with SEM morphology observation and energy disperse spectroscopy (EDS).The results showed that Pt/Ta composite anode could load large current density.Electrochemical catalytic activity of the anode decreased relatively and the charge transfer resistance of Faradaic process increased evidently at low temperatures.The surface microcrak and the gas evalufron from working anode accelerated the dissolution of anode.
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