Effect of Niobium Content on Microstructure Evolution of HR3C Steel During High Temperature Aging
摘 要
在HR3C钢化学成分的基础上调整铌元素的质量分数分别为0.5%,0.8%和1.1%,熔炼得到3种成分钢锭,再进行热轧、1 200℃均匀化退火和固溶处理、750℃不同时间(0~2 000 h)时效处理,研究了铌含量对试验钢显微组织、晶粒尺寸和硬度的影响。结果表明:增加铌含量将提高固溶态试验钢中未溶MX相的含量,减小晶粒尺寸;在750℃时效过程中,增加铌含量会促进σ相在晶界和晶内的析出和粗化,提高硬度;在时效2 000 h时铌含量对晶界析出相的尺寸和分布影响不大,但对晶内析出相的尺寸和形态有所影响,铌质量分数1.1%试验钢中晶内析出相的数量相对较少且呈条状。
Abstract
On the basis of the chemical composition of HR3C steel, the mass fractions of niobium element were adjusted to 0.5%, 0.8% and 1.1%, respectively. The ingot samples with the three components were obtained by melting, and then subjected to hot rolling, homogenization annealing at 1 200℃, solid solution at 1 200℃, and aging at 750℃ for different times (0-2 000 h). The effects of niobium content on the microstructure, grain size and hardness of the test steel were studied. The results show that increasing the niobium content could increase the content of undissolved MX phase in the solid solution test steel and reduce the grain size. During aging at 750℃, increasing the niobium content could promote the precipitation and coarsening of σ phase at grain boundaries and inside grains, and improve the hardness. When aging for 2 000 h, the niobium content had little effect on the size and distribution of grain boundary precipitates, but had some influence on the size and shape of intragranular precipitates; the test steel containing 1.1wt% niobium had a relatively small number of strip-like intragranular precipitates.
中图分类号 TG142.1+3 DOI 10.11973/jxgccl202302005
所属栏目 试验研究
基金项目 国家自然科学基金资助项目(51901035,U1610256)
收稿日期 2022/2/10
修改稿日期 2022/12/27
网络出版日期
作者单位点击查看
备注杨聪辉(1997-),男,山东烟台人,硕士研究生
引用该论文: YANG Conghui,CAO Tieshan,CHEN Xiangang,CHENG Congqian,ZHAO Jie. Effect of Niobium Content on Microstructure Evolution of HR3C Steel During High Temperature Aging[J]. Materials for mechancial engineering, 2023, 47(2): 26~32
杨聪辉,曹铁山,陈献刚,程从前,赵杰. 铌含量对HR3C钢在高温时效过程中显微组织演变的影响[J]. 机械工程材料, 2023, 47(2): 26~32
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】KERN T U, STAUBLI M, SCARLIN B.The European efforts in material development for 650℃ USC power plants:COST522[J].ISIJ International, 2002, 42(12):1515-1519.
【2】ABE F.Research and development of heat-resistant materials for advanced USC power plants with steam temperatures of 700℃ and above[J].Engineering, 2015, 1(2):211-224.
【3】BAI X, PAN J, CHEN G, et al.Effect of high temperature aging on microstructure and mechanical properties of HR3C heat resistant steel[J].Energy Materials, 2014, 9(2):205-210.
【4】LI Y, WANG X.Strengthening mechanisms and creep rupture behavior of advanced austenitic heat resistant steel SA-213 S31035 for A-USC power plants[J].Materials Science and Engineering:A, 2020, 775:138991.
【5】白佳铭.Co、Cr、C对改性HR3C长期时效组织及力学性能的影响[D].西安:西安理工大学, 2019. BAI J M.Effect of Co, Cr and C on microstructure and mechanical properties of modified HR3C during long-term aging[D].Xi'an:Xi'an University of Technology, 2019.
【6】SUN F, GU Y F, YAN J B, et al.Phenomenological and microstructural analysis of intermediate temperatures creep in a Ni-Fe-based alloy for advanced ultra-supercritical fossil power plants[J].Acta Materialia, 2016, 102:70-78.
【7】BOISSONNET G, BOULESTEIX C, BONNET G, et al.Thermal transport properties of new coatings on steels for supercritical steam power plants[J].Oxidation of Metals, 2017, 88(1/2):191-202.
【8】PEDRAZA F, BOULESTEIX C, PROY M, et al.Behavior of slurry aluminized austenitic stainless steels under steam at 650 and 700℃[J].Oxidation of Metals, 2017, 87(3/4):443-454.
【9】LU Y, WANG Q, WEN D, et al.Microstructural stability of Ta minor-alloying HR3C stainless steel at 973 K[J].Materials Chemistry and Physics, 2020, 239:122306.
【10】ZIELIŃSKI A.Evolution of the microstructure and mechanical properties of HR3C austenitic stainless steel after ageing for up to 30, 000 h at 650-750℃[J].Materials Science and Engineering:A, 2020, 796:139944.
【11】BAI J M, YUAN Y, ZHANG P, et al.Precipitation behavior of high-Nb containing modified HR3C heat-resistant steels during isothermal aging[J].Materials Science and Technology, 2019, 35(14):1717-1726.
【12】CAO T S, CHENG C Q, ZHAO J, et al.Precipitation behavior of σ phase in ultra-supercritical boiler applied HR3C heat-resistant steel[J].Acta Metallurgica Sinica (English Letters), 2019, 32(11):1355-1361.
【13】刘世刚, 黄桥生, 陈琨.1000 MW超超临界机组高温再热器管弯头失效分析[J].电力科技与环保, 2017, 33(2):60-62. LIU S G, HUANG Q S, CHEN K.Failure analysis on the elbow bursting of final stage reheater tube of 1000 MW ultra-supercritical boiler[J].Electric Power Technology and Environmental Protection, 2017, 33(2):60-62.
【14】ZHU C Z, YUAN Y, ZHANG P, et al.A modified HR3C austenitic heat-resistant steel for ultra-supercritical power plants applications beyond 650℃[J].Metallurgical and Materials Transactions A, 2018, 49(2):434-438.
【15】YAN J B.Evolution of microstructure and mechanical properties of a 25Cr-20Ni heat resistant alloy after long-term service[J].Materials Science and Engineering:A, 2016, 675:289-298.
【16】王志武, 宋涛.不同含量Cr、Ni、Nb的HR3C钢热力学平衡相分析[J].武汉大学学报(工学版), 2020, 53(11):1028-1034. WANG Z W, SONG T.Thermodynamic equilibrium phase analysis of HR3C steel with different Cr, Ni and Nb contents[J].Engineering Journal of Wuhan University, 2020, 53(11):1028-1034.
【17】WANG J L, MENG B, LU J T, et al.Studies on the oxidation behavior and microstructural evolution of two Nb-modified HR3C austenitic steels under pure water vapor at 650℃[J].Materials (Basel, Switzerland), 2020, 13(23):5447.
【18】刘祥, 杜群力, 李新.加热工艺对Nb-Ti微合金钢奥氏体晶粒长大的影响[J].钢铁, 2019, 54(9):116-120. LIU X, DU Q L, LI X.Effect of heating process on grain growth of Nb-Ti microalloyed steel[J].Iron & Steel, 2019, 54(9):116-120.
【19】王云鹏, 胡嘉玮, 许小云, 等.多向锻造对铝合金组织与性能影响的研究进展[J].材料导报, 2019, 33(13):2266-2271. WANG Y P, HU J W, XU X Y, et al.Research progress of effect of multi-directional forging on microstructure and properties of aluminum alloys[J].Materials Reports, 2019, 33(13):2266-2271.
【20】YUAN S Q, LIANG G L.Dissolving behaviour of second phase particles in Nb-Ti microalloyed steel[J].Materials Letters, 2009, 63(27):2324-2326.
【21】BERGMAN G, SHOEMAKER D P.The determination of the crystal structure of the σ phase in the iron-chromium and iron-molybdenum systems[J].Acta Crystallographica, 1954, 7(12):857-865.
【22】BAI J M, YUAN Y, ZHANG P, et al.Effect of carbon on microstructure and mechanical properties of HR3C type heat resistant steels[J].Materials Science and Engineering:A, 2020, 784:138943.
【23】WANG R M, DUAN M G, ZHANG J, et al.Microstructure characteristics and their effects on the mechanical properties of as-served HR3C heat-resistant steel[J].Journal of Materials Engineering and Performance, 2021, 30(6):4552-4561.
【2】ABE F.Research and development of heat-resistant materials for advanced USC power plants with steam temperatures of 700℃ and above[J].Engineering, 2015, 1(2):211-224.
【3】BAI X, PAN J, CHEN G, et al.Effect of high temperature aging on microstructure and mechanical properties of HR3C heat resistant steel[J].Energy Materials, 2014, 9(2):205-210.
【4】LI Y, WANG X.Strengthening mechanisms and creep rupture behavior of advanced austenitic heat resistant steel SA-213 S31035 for A-USC power plants[J].Materials Science and Engineering:A, 2020, 775:138991.
【5】白佳铭.Co、Cr、C对改性HR3C长期时效组织及力学性能的影响[D].西安:西安理工大学, 2019. BAI J M.Effect of Co, Cr and C on microstructure and mechanical properties of modified HR3C during long-term aging[D].Xi'an:Xi'an University of Technology, 2019.
【6】SUN F, GU Y F, YAN J B, et al.Phenomenological and microstructural analysis of intermediate temperatures creep in a Ni-Fe-based alloy for advanced ultra-supercritical fossil power plants[J].Acta Materialia, 2016, 102:70-78.
【7】BOISSONNET G, BOULESTEIX C, BONNET G, et al.Thermal transport properties of new coatings on steels for supercritical steam power plants[J].Oxidation of Metals, 2017, 88(1/2):191-202.
【8】PEDRAZA F, BOULESTEIX C, PROY M, et al.Behavior of slurry aluminized austenitic stainless steels under steam at 650 and 700℃[J].Oxidation of Metals, 2017, 87(3/4):443-454.
【9】LU Y, WANG Q, WEN D, et al.Microstructural stability of Ta minor-alloying HR3C stainless steel at 973 K[J].Materials Chemistry and Physics, 2020, 239:122306.
【10】ZIELIŃSKI A.Evolution of the microstructure and mechanical properties of HR3C austenitic stainless steel after ageing for up to 30, 000 h at 650-750℃[J].Materials Science and Engineering:A, 2020, 796:139944.
【11】BAI J M, YUAN Y, ZHANG P, et al.Precipitation behavior of high-Nb containing modified HR3C heat-resistant steels during isothermal aging[J].Materials Science and Technology, 2019, 35(14):1717-1726.
【12】CAO T S, CHENG C Q, ZHAO J, et al.Precipitation behavior of σ phase in ultra-supercritical boiler applied HR3C heat-resistant steel[J].Acta Metallurgica Sinica (English Letters), 2019, 32(11):1355-1361.
【13】刘世刚, 黄桥生, 陈琨.1000 MW超超临界机组高温再热器管弯头失效分析[J].电力科技与环保, 2017, 33(2):60-62. LIU S G, HUANG Q S, CHEN K.Failure analysis on the elbow bursting of final stage reheater tube of 1000 MW ultra-supercritical boiler[J].Electric Power Technology and Environmental Protection, 2017, 33(2):60-62.
【14】ZHU C Z, YUAN Y, ZHANG P, et al.A modified HR3C austenitic heat-resistant steel for ultra-supercritical power plants applications beyond 650℃[J].Metallurgical and Materials Transactions A, 2018, 49(2):434-438.
【15】YAN J B.Evolution of microstructure and mechanical properties of a 25Cr-20Ni heat resistant alloy after long-term service[J].Materials Science and Engineering:A, 2016, 675:289-298.
【16】王志武, 宋涛.不同含量Cr、Ni、Nb的HR3C钢热力学平衡相分析[J].武汉大学学报(工学版), 2020, 53(11):1028-1034. WANG Z W, SONG T.Thermodynamic equilibrium phase analysis of HR3C steel with different Cr, Ni and Nb contents[J].Engineering Journal of Wuhan University, 2020, 53(11):1028-1034.
【17】WANG J L, MENG B, LU J T, et al.Studies on the oxidation behavior and microstructural evolution of two Nb-modified HR3C austenitic steels under pure water vapor at 650℃[J].Materials (Basel, Switzerland), 2020, 13(23):5447.
【18】刘祥, 杜群力, 李新.加热工艺对Nb-Ti微合金钢奥氏体晶粒长大的影响[J].钢铁, 2019, 54(9):116-120. LIU X, DU Q L, LI X.Effect of heating process on grain growth of Nb-Ti microalloyed steel[J].Iron & Steel, 2019, 54(9):116-120.
【19】王云鹏, 胡嘉玮, 许小云, 等.多向锻造对铝合金组织与性能影响的研究进展[J].材料导报, 2019, 33(13):2266-2271. WANG Y P, HU J W, XU X Y, et al.Research progress of effect of multi-directional forging on microstructure and properties of aluminum alloys[J].Materials Reports, 2019, 33(13):2266-2271.
【20】YUAN S Q, LIANG G L.Dissolving behaviour of second phase particles in Nb-Ti microalloyed steel[J].Materials Letters, 2009, 63(27):2324-2326.
【21】BERGMAN G, SHOEMAKER D P.The determination of the crystal structure of the σ phase in the iron-chromium and iron-molybdenum systems[J].Acta Crystallographica, 1954, 7(12):857-865.
【22】BAI J M, YUAN Y, ZHANG P, et al.Effect of carbon on microstructure and mechanical properties of HR3C type heat resistant steels[J].Materials Science and Engineering:A, 2020, 784:138943.
【23】WANG R M, DUAN M G, ZHANG J, et al.Microstructure characteristics and their effects on the mechanical properties of as-served HR3C heat-resistant steel[J].Journal of Materials Engineering and Performance, 2021, 30(6):4552-4561.
相关信息