Effect of w(Ti+B4C+C)/w(Ni60A) on Structure and Performance ofNickel-Based Composite Coating by Plasma Cladding
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摘 要
以Ni60A合金粉、钛(Ti)粉、石墨(C)粉和B4C粉为原料,其中w(Ti+B4C+C)/w(Ni60A)(w为质量分数/%)分别为0:100,10:90,20:80,30:70,采用反应等离子熔覆技术在304不锈钢表面制备镍基复合涂层,研究了w(Ti+B4C+C)/w(Ni60A)对涂层成形性、显微组织、硬度和耐磨性能的影响。结果表明:添加Ti+B4C+C的镍基复合涂层与基体呈冶金结合,且主要由(Ni,Fe)、CrB、TiC和Cr3Si相组成;增大w(Ti+B4C+C)/w(Ni60A)会增加强化相析出量,降低成形性;CrB在涂层中下部呈灰黑色细长条状,在上部呈细小块状或棒状,TiC主要以细小颗粒弥散分布于涂层中;当w(Ti+B4C+C)/w(Ni60A)为20:80时,涂层综合性能较优,平均显微硬度最高(948 HV),磨痕截面面积约为纯Ni60A合金涂层的1/5;镍基复合涂层主要发生黏着磨损和氧化磨损。
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Abstract
With Ni60A alloy, Ti, graphite (C), and B4C powders as raw materials and adjusting w(Ti+B4C+C)/w(Ni60A) (w is mass fraction/%) to 0:100, 10:90, 20:80 and 30:70, nickel-based composite coatings were synthesized by reactive plasma cladding on surface of 304 stainless steel. The effects of w(Ti+B4C+C)/w(Ni60A) on the formability, microstructure, hardness and wear resistance of the coating were studied. The results show that the nickel-based composite coatings with Ti+B4C+C were metallurgically bonded to the substrate, and were mainly composed of (Ni, Fe), CrB, TiC and Cr3Si. Increasing w(Ti+B4C+C)/w(Ni60A) improved the precipitation of strengthening phases and decreased the formability. CrB dispersed in the middle and lower part of the coating in gray-black slender strip forms, while in the upper part in small block or rod forms. TiC dispersed in the coating in fine particle forms. When w(Ti+B4C+C)/w(Ni60A) was 20:80, the comprehensive performance of the coating was relatively good; the average microhardness was the highest (948 HV) and the cross-sectional area of the wear scar was about 1/5 that of the pure Ni60A alloy coating. Adhesive wear and oxidative wear mainly occurred in nickel-based composite coatings.
中图分类号 TG178 DOI 10.11973/jxgccl202105003
所属栏目 试验研究
基金项目 南通市市级科技计划项目(JC2018113);中央高校基本科研业务费项目(2017B16114,B200205001)
收稿日期 2021/1/27
修改稿日期 2021/4/8
网络出版日期
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备注薛春旭(1996-),男,江苏南通人,硕士研究生
引用该论文: XUE Chunxu,JIANG Shaoqun,WANG Gang,WANG Zehua,ZHOU Zehua. Effect of w(Ti+B4C+C)/w(Ni60A) on Structure and Performance ofNickel-Based Composite Coating by Plasma Cladding[J]. Materials for mechancial engineering, 2021, 45(5): 15~21
薛春旭,江少群,王刚,王泽华,周泽华. w(Ti+B4C+C)/w(Ni60A)对等离子熔覆镍基复合涂层结构与性能的影响[J]. 机械工程材料, 2021, 45(5): 15~21
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【9】戴军,宋玮琦,张杰,等.热处理对等离子熔覆钴基涂层组织及性能的影响[J].热加工工艺,2015,44(22):194-196. DAI J,SONG W Q,ZHANG J,et al.Effect of heat treatment on microstructure and properties of Co-based coating by plasma cladding[J].Hot Working Technology,2015,44(22):194-196.
【10】GONG J X,LU J B,LIU Y.Microstructure analysis of TiC reinforced Ni-based composite coating by plasma cladding[J].Advanced Materials Research,2012,538/539/540/541:286-289.
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【13】江少群,王刚,吕长月.(Ti+B4C)/Fe901比对等离子熔覆铁基涂层结构及硬度的影响[J].表面技术,2017,46(9):26-31. JIANG S Q,WANG G,LYU C Y.Effect of (Ti+B4C)/Fe901 ratio on microstructure and microhardness of Fe-based coatings synthesized by plasma cladding[J].Surface Technology,2017,46(9):26-31.
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