Effect of V Addition Amount on Microstructure and Mechanical Properties of Mo2FeB2-Based Cermets
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摘 要
采用真空液相烧结技术制备了Mo2FeB2基金属陶瓷,研究了钒添加量(质量分数,0~7.5%)对其组织和力学性能的影响。结果表明:当钒添加量不大于2.5%时,金属陶瓷的孔隙率无明显变化,当钒添加量大于2.5%时,金属陶瓷中的孔隙明显增多,金属陶瓷的致密性下降;钒的添加对金属陶瓷的相组成无显著影响,Mo2FeB2硬质相均匀分布在铁基黏结相中;当钒添加量为2.5%时,硬质相呈长条状且明显细化;当钒添加量大于2.5%时,硬质相发生团聚,且形貌由长条状向等轴状转变;随着钒添加量的增加,金属陶瓷的硬度、抗弯强度和断裂韧度均先增后降,当钒添加量为2.5%时均达到最大值,分别为90.6 HRA、2 350 MPa和15.1 MPa·m1/2。
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Abstract
Mo2FeB2-based cermets were prepared by vacuum liquid phase sintering technique. The effect of V addition amount (0-7.5wt%) on the microstructure and mechanical properties of cermets was investigated. The results show that the porosity of cermets had little change when V addition amount was not more than 2.5wt%. When V addition amount was more than 2.5wt%, pores in cermets increased obviously and the relative density of cermets decreased. V addition had no effect on the phase composition of cermets, and Mo2FeB2 hard phase was uniformly distributed in the iron-base bonding phases. When the V addition amount was 2.5wt%, hard phase was long ribbon shape and was obviously refined. When V addition amount exceeded 2.5wt%, hard phase agglomerated and its morphology changed from long ribbon shape to equiaxial shape. With the increase of V addition amount, the hardness, rupture strength and fracture toughness all first increased and then decreased, and reached their maximum values with V addition amount of 2.5wt%, which were 90.6 HRA, 2 350 MPa and 15.1 MPa·m1/2, respectively.
中图分类号 TB33 DOI 10.11973/jxgccl201911008
所属栏目 材料性能及应用
基金项目 国家自然科学基金资助项目(NSFC-51602145);江苏省博士后基金资助项目
收稿日期 2018/11/13
修改稿日期 2019/10/12
网络出版日期
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备注李万发(1997-),男,江苏徐州人,硕士研究生
引用该论文: LI Wanfa,ZHOU Jia,WANG Hao,LV Xuepeng,ZHENG Yong. Effect of V Addition Amount on Microstructure and Mechanical Properties of Mo2FeB2-Based Cermets[J]. Materials for mechancial engineering, 2019, 43(11): 32~36
李万发,周佳,王浩,吕学鹏,郑勇. 钒添加量对Mo2FeB2基金属陶瓷显微组织和力学性能的影响[J]. 机械工程材料, 2019, 43(11): 32~36
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参考文献
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【4】KOMAI M, ISOBE Y, OZAKI S, et al. Effects of Cr on the microstructure and mechanical properties of WCoB base hard alloys[J]. Journal of the Japan Society of Powder and Powder Metallurgy, 1993, 40(1):38-43.
【5】庞旭明, 郑勇, 承新. 反应烧结法制备Mo2FeB2基金属陶瓷的研究[J]. 硬质合金, 2008, 25(2):73-77.
【6】郑建智, 郑勇, 庞旭明, 等. Mo2FeB2基金属陶瓷烧结过程中显微组织和力学性能的变化[J]. 硬质合金, 2009, 26(2):65-70.
【7】王永国, 李兆前, 张荻. 新型三元硼化物基金属陶瓷的研究[J]. 无机材料学报, 2003, 18(6):1217-1221.
【8】李阳, 余海洲, 赵迪, 等. 热等静压对Mo2FeB2基金属陶瓷的组织及性能的影响[J]. 金属热处理, 2017(5):112-116.
【9】余海洲, 刘文俊, 张明松, 等. Mo2FeB2基金属陶瓷的相变及其显微组织演变研究I:相变[J]. 硬质合金, 2011, 28(3):137-142.
【10】PANG X M, ZHENG Y, WANG S G, et al. Effect of Mn on valence-electron structure and properties of hard phase in Mo2FeB2-based cermets[J]. International Journal of Refractory Metals and Hard Materials,2009,27(4):777-780.
【11】YU H Z, ZHENG Y, LIU W J, et al. Effect of Mn content on the microstructure and mechanical properties of Mo2FeB2 based cermets[J]. International Journal of Refractory Metals and Hard Materials, 2010, 28(2):286-290.
【12】严孟凯, 季根顺, 马文林, 等. 合金元素对Mo2FeB2基金属陶瓷组织及性能的影响[J].粉末冶金技术,2014(4):243-247.
【13】陶则旭, 从善海, 彭家健, 等. 多组元硬质相增强Mo2FeB2基金属陶瓷的组织和性能研究[J]. 粉末冶金工业, 2018(3):44-47.
【14】TAKAGI K. Development and application of high strength ternary boride base cermets[J]. Journal of Solid State Chemistry, 2006, 179(9):2809-2818.
【2】TAKAGI K. High tough boride base cermets produced by reaction sintering[J]. Materials Chemistry and Physics, 2001, 67(3):214-219.
【3】TAKAGI K, YAMASAKI Y.Effects of Mo/B atomic ratio on the mechanical properties and structure of Mo2NiB2 boride base cermets with Cr and V additions[J]. Journal of Solid State Chemistry, 2000, 154(1):263-268.
【4】KOMAI M, ISOBE Y, OZAKI S, et al. Effects of Cr on the microstructure and mechanical properties of WCoB base hard alloys[J]. Journal of the Japan Society of Powder and Powder Metallurgy, 1993, 40(1):38-43.
【5】庞旭明, 郑勇, 承新. 反应烧结法制备Mo2FeB2基金属陶瓷的研究[J]. 硬质合金, 2008, 25(2):73-77.
【6】郑建智, 郑勇, 庞旭明, 等. Mo2FeB2基金属陶瓷烧结过程中显微组织和力学性能的变化[J]. 硬质合金, 2009, 26(2):65-70.
【7】王永国, 李兆前, 张荻. 新型三元硼化物基金属陶瓷的研究[J]. 无机材料学报, 2003, 18(6):1217-1221.
【8】李阳, 余海洲, 赵迪, 等. 热等静压对Mo2FeB2基金属陶瓷的组织及性能的影响[J]. 金属热处理, 2017(5):112-116.
【9】余海洲, 刘文俊, 张明松, 等. Mo2FeB2基金属陶瓷的相变及其显微组织演变研究I:相变[J]. 硬质合金, 2011, 28(3):137-142.
【10】PANG X M, ZHENG Y, WANG S G, et al. Effect of Mn on valence-electron structure and properties of hard phase in Mo2FeB2-based cermets[J]. International Journal of Refractory Metals and Hard Materials,2009,27(4):777-780.
【11】YU H Z, ZHENG Y, LIU W J, et al. Effect of Mn content on the microstructure and mechanical properties of Mo2FeB2 based cermets[J]. International Journal of Refractory Metals and Hard Materials, 2010, 28(2):286-290.
【12】严孟凯, 季根顺, 马文林, 等. 合金元素对Mo2FeB2基金属陶瓷组织及性能的影响[J].粉末冶金技术,2014(4):243-247.
【13】陶则旭, 从善海, 彭家健, 等. 多组元硬质相增强Mo2FeB2基金属陶瓷的组织和性能研究[J]. 粉末冶金工业, 2018(3):44-47.
【14】TAKAGI K. Development and application of high strength ternary boride base cermets[J]. Journal of Solid State Chemistry, 2006, 179(9):2809-2818.
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