Performance and Electrodeposition Process of Nanocrystalline Ni-W-RE Alloy Coatings
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摘 要
采用电沉积技术制备了纳米晶镍-钨-稀土合金镀层,重点研究了其制备工艺及镀层性能,探讨了电流密度、电沉积时间、镀液中稀土含量、镀液pH值和镀液温度等因素对镀层沉积速率的影响;用SEM、XRD、EDS、阳极极化曲线等方法分析了镀层的表面形貌、结构、组成、耐蚀性和抗氧化性等.结果表明:合金镀层的最佳制备工艺条件为电流密度9.5 A·dm-2、镀液pH值7、电沉积时间70 min、镀液温度50 ℃、镀液中NdCl3添加量4.5 g·L-1或镀液中Ce(SO4)2添加量3 g·L-1;添加稀土元素钕、铈后合金镀层表面颗粒排列致密、均匀,表面无裂纹,其抗高温氧化性和耐蚀性能与硬铬镀层比较相差较小.
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Abstract
Nanocrystalline Ni-W-RE alloy coatings were prepared by electrodeposition and the performance and preparation technology were studied.The effects of current density,time of deposition,RE content in plating solution,pH value and temperature on the deposition rate of the coatings were studied.Surface morphology,structure,composition,corrosion resistance and oxidation resistance of composite coatings were tested by SEM,XRD,EDS and anodic polarization curves etc.The results show that the optimized preparation conditions of composite coatings were current density 9.5 A·dm-2,pH=7,time of electrodeposition 70 min,temperature of the solution 50 ℃,NdCl3 content in the solution 4.5 g·L-1 and Ce(SO4)2 content 3 g·L-1.The surface grains of the alloy coatings arranged densely,uniformly and without cracks after adding the RE elements of Nd and Ce.And the high temperature oxidation resistance and corrosion resistance of Ni-W-Nd alloy coatings were only a littre different from those of the hard chromium plating.
中图分类号 TQ153.1
所属栏目 纳米材料
基金项目 广西自然科学基金资助项目(0731015)
收稿日期 2009/4/29
修改稿日期 2009/11/29
网络出版日期
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备注刘峥(1962-),女,江西兴国人,教授,博士.
引用该论文: LIU Zhen,ZHANG Xue-hui,ZHANG Jian-zhang. Performance and Electrodeposition Process of Nanocrystalline Ni-W-RE Alloy Coatings[J]. Materials for mechancial engineering, 2010, 34(5): 76~80
刘峥,张学会,张建章. 电沉积制备纳米晶镍-钨-稀土合金镀层工艺及性能[J]. 机械工程材料, 2010, 34(5): 76~80
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参考文献
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【4】郑子樵,李红英.稀土功能材料[M].北京:化学工业出版社,2003:460-466.
【5】LOKHANDE C D.Electrodepo sition of samarium[J].Metal Finishing,1988(8):23-28.
【6】LOKHANDE C D.Electrodepo sition of lanthanum from aqueous baths[J].Metal Finishing,1988(8):53-57.
【7】JUNDHAL E S B.Electrodepo sition of samarium from tartrate bath[J].Materials Chemistry and Physics,1991,27:265-269.
【8】刘淑兰,覃奇贤,成旦红,等.电沉积Ni-La合金上的阴极析氢行为[J].应用化学,1995,12(5):115-118.
【9】李振良,杨防祖,姚士冰.镍钨合金电结晶机理[J].厦门大学学报:自然科学版,1999,38(2):230-234.
【10】朱明华,李立青.稀土添加剂在金属电沉积中的应用研究进展[J].电镀与涂饰,2006,25(6):46-48.
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